For intra-workout I like BCAAs (and USP's new Modern BCAA looks like it'll take the cake - I'll post about it whenever I get them and start using). Currently intra I use a 4:1:1 blend from TruNutrition (total of 24:6:6 & 10g creatine monohydrate). I like EAAs (and BCAAs, but to a lesser extent) for daytime usage. Right now I take LG's BC+EAA pre-workout (about 75 minutes after my pre-workout meal). I'd also use that blend for during the day, immediately after waking and immediately before bed when I'm on a real strict cut. Purple Wraath also has a pretty good profile for that and VPX's PowerShock looks decent (actually have some coming to me to test out, so I'll post on that as well).