IMO, if you are only starting out and your goal is to get larger, thicker, stronger and more powerful, then programs utilizing the big 5-7 compound lifts first and foremost are best.
Squatting
Leg Pressing
Bench Pressing
Deadlifting
Standing Overhead or Military pressing
Bent Rowing
Dips (some guys can get a good bit out of dips without shoulder problems, other guys are not so lucky)
Chins/pull ups/pull downs
Incline Presses
Leg raises or ab or trunk work
etc.
These compound exercises work the entire largest structures and mass of the body, both muscle wise and systemically. (building fitness, lung capacity, work capacity etc.) You do not have to do them all in a program/routine, but they are very effective ones to add mass and power all over the body.
Since you are relatively new to W/O's, then keeping the sets around 3-4 and rep ranges between 8-12, will build muscle, along with giving you time before going too heavy (in say a 5x5) plus you learn the forms and your leverages with more manageable weights, (especially in say squatting and or deadlifting.)
Focus on those first, then at the end of W/O's, do your smaller stuff, or isolation moves.
Combine those with healthy eating and resting and you will grow.