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Sodium tert butoxide

  1.  07-13-2004  04:40 AM
    Registered User Granger's Avatar
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    Sodium tert butoxide


    Ok, i seem to understand there are two syno coversions, one using lye, which yields TNE, the other using STB, which yields T-prop. I found a link that sells STB, but how, and how much to use?

    https://www1.fishersci.com/Coupon?gid=192235&cid=1334



  2.  07-17-2004  04:11 AM
    Registered User Granger's Avatar
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    ok, didnt mean to step on D's toes...my bad.
    i know that EB is a phenol and TP is not, and because of its acidity<sp> can be made soluble in water with a base substance. Bicarbonate is too weak to be effective,if at all, and lye is too strong to leave the esters on the target substance. Im just looking for the "happy medium"....<pun>.

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  3.  07-18-2004  04:53 PM
    Registered User Andy13's Avatar
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    Originally Posted by Granger
    ok, didnt mean to step on D's toes...my bad.
    i know that EB is a phenol and TP is not, and because of its acidity<sp> can be made soluble in water with a base substance. Bicarbonate is too weak to be effective,if at all, and lye is too strong to leave the esters on the target substance. Im just looking for the "happy medium"....<pun>.
    Shhh !


    Actually, EB is esterified at its phenol-OH rather than the allicyclic OH. If it were the other way around, simple carbonate extraction would ionize and remove the phenol...

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