I would work it in this order,
Standing Barbell Curls/Preacher curls
Standing Calf Raises/Seated Calf Raises
You might have a hard time doing Dips so late in the workout, you could move them up with benchpress with a forward lean and still be fresh for them. Also dont forget your core ABB work.
The 4500-5K cals seems like a lot, but hard to say without your weight/Ht.