You can IF you use an unscented product, OR if the scented `mone you are mixing with compliments the cologne you are using. The `mones will alter the scent of your cologne, but not to a huge degree unless you are OD'ing on the `mones.
It depends on the individual and the scenario they are attempting to have success in. They are also not a "magic bullet" that will take care of everything for you. You need to have a good amount of social skills. They are just an edge over someone equally as attractive and socially adept as you in all reality, or an equalizer of sorts if they are more attractive, but you really can't compensate for a lack of social skills no matter what. I suggest reading around the FAQs and such at love-scent before buying, and don't ask this question there because you will get the same answers I have given you.
NPA is the strongest, in terms of sexual results with TE (a dilute form of NPA) right behind. These add a musky base note to your colognes so use judiciously.
AE is another strong one but produces more unpredictable and sometimes negative results.
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