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Yohimbine is a tremendous fat-burning compounds and stimulant that works by increasing adrenaline levels in the body, as well as inhibiting a regulatory process in fat cells, which normally suppresses fat burning. Its typical practice to utilize it fasted as its effects are partially negated by food. I'm a big proponent of utilizing it fasted as well as between meals (as long as your nutrient timing in up to par and needs to be specialized to accommodate this addition.)
Basic dosages in research show to dose roughly 0.2mg/kg bodyweight. Meaning, if your a 200 lb bodybuilder, you'll want to utilize around 18 mgs (do not jump up to the max dosage right away but rather assess your tolerance at 40% of the recommended dosage and build up overtime as you see how you handle it.)
Yohimbine: the effects on body composition and exercise performance in soccer players. - PubMed - NCBI
Psychological and neuroendocrine responses to social stress and to the administration of the alpha-2-receptor antagonist, yohimbine, in highly trai... - PubMed - NCBI
Effects of yohimbine on cerebral blood flow, symptoms, and physiological functions in humans. - PubMed - NCBI